A unified and common intermediate strategy for the asymmetric total synthesis of 3-deoxy-neo-inositol and conduritol E
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Date
2016
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Abstract
A competent, simplistic, and unified synthetic approach has been outlined for enantiomerically pure 3-deoxy-neo-inositol and conduritol E starting from D-ribose via a common chiral cyclohexenol derivative. The focal attributes of the synthetic route include stereoselective Grignard reaction, Wittig olefination, ring closing metathesis (RCM), and cis dihydroxylation. � 2016
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Keywords
3-Deoxy-neo-inosotol, Asymmetric synthesis, Carbocycles, Common intermediate, Conduritol E
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